inner sphere electron transfer

How Does Inner Sphere Electron Transfer Differ from Outer Sphere Electron Transfer?

In contrast to inner sphere electron transfer, outer sphere electron transfer occurs without any direct bonding between the donor and acceptor. In outer sphere mechanisms, the electron hops through space or through solvent molecules, making the process generally slower and more sensitive to the medium's properties. Inner sphere transfer, involving a direct coordination bond, is often faster and more efficient.

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