oxidative addition and reductive elimination

What Factors Influence Reductive Elimination?


Reductive elimination is influenced by the electronic and steric environment around the metal center. Electron-deficient metals and bulky ligands often promote reductive elimination by making the metal more electrophilic and by reducing steric hindrance for the departing groups. The nature of the leaving groups also plays a critical role; for instance, reductive elimination is generally faster when the leaving groups form a stable product, such as a stable organic molecule or gas.

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