binap (2,2' bis(diphenylphosphino) 1,1' binaphthyl)

How Does BINAP Function as a Ligand?

The effectiveness of BINAP as a ligand arises from its ability to coordinate to metal centers, forming stable complexes. The bidentate nature of BINAP allows it to bind to a metal via both phosphorus atoms, creating a rigid and well-defined coordination environment. This rigidity is crucial for inducing chirality in the catalytic process, as it ensures the proper alignment of substrates and intermediates.

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