How do Electrochemical Conditions Affect Catalytic Activity?
Electrochemical conditions can significantly impact the activity of a catalyst. For instance, the applied potential can alter the adsorption properties of reactants on the catalyst surface, thus affecting the reaction pathway. The current density influences the rate of electron transfer, while the composition of the electrolyte can affect the availability of reactive species. Moreover, the pH of the electrolyte can alter the protonation state of intermediates, influencing the reaction kinetics.