mars van krevelen mechanism

What are the key features of the Mars-van Krevelen mechanism?

Several key features distinguish the MvK mechanism:
Lattice oxygen participation: The MvK mechanism uniquely involves the transfer of oxygen from the catalyst’s lattice to the substrate.
Role of oxygen vacancies: Oxygen vacancies play a crucial role, as they need to be replenished to maintain catalytic activity.
Surface reactions: The reactions occur on the surface of the catalyst, emphasizing the importance of surface properties.
Reversibility: The catalyst undergoes reversible oxidation and reduction cycles.

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