Do Rotational Excited States Impact Selectivity in Catalysis?
Rotational excited states can indeed impact the selectivity of catalytic reactions. The orientation and energy distribution of reactant molecules in excited states can favor different reaction pathways, leading to varying products. For example, in enantioselective catalysis, rotational states can influence the formation of specific enantiomers, thus affecting the enantiomeric excess and overall selectivity.
