Yes, bond lengths and angles can be tuned through various strategies: 1. Ligand Modification: Changing the ligands in a coordination complex can alter the bond angles and lengths around the central metal atom. 2. Pressure and Temperature: External conditions such as pressure and temperature can also affect bond lengths and angles, thereby influencing catalytic activity. 3. Substrate Engineering: In heterogeneous catalysis, the surface structure of the catalyst can be engineered to optimize the bond lengths and angles for specific reactions.