Why is the Electronic Structure Important for Selectivity?
Selectivity in catalysis is the ability of the catalyst to favor the formation of a particular product over others. The electronic structure of the catalyst can determine its selectivity by influencing the adsorption energies of different reactants and intermediates. Catalysts with tailored electronic structures can preferentially stabilize certain intermediates, leading to the desired product. For example, catalysts with a particular d-band center can selectively adsorb certain molecules, enhancing selectivity.
